碾压混凝土直剪试件细观结构的数值模拟

从细观层次上将碾压混凝土试件当作是由硬化水泥粉煤灰砂浆、粗骨料、二者间的粘结带以及水泥砂浆中间层面组成的非均质复合材料，由随机骨料模型模拟碾压混凝土的细观结构，用非线性有限元法模拟试件在直剪作用下的细观损伤断裂，从而求得其宏观抗剪断强度，计算结果与《混凝土重力坝设计规范》所提供的参考值较为吻合，据此还进行了试件破坏机理分析，应用此种计算方法，可节省直剪试验工作量，并可进行直剪试件的尺寸效应分析，有广阔的应用前景。     

拱坝表面温度裂缝的成因及稳定性分析

结合混凝土材料特性，分析了拱坝表面温度裂缝的成因，对其混凝土温度过程、温度应力过程进行了分析计算。在此基础上，应用线性断裂力学的方法对表面温度裂缝的稳定性进行了分析，提出了相关的结论。     

鲁米诺-H2O2-CuSO4体系中针剂维生素C的抗自由基活性

采用鲁米诺 H2 O2 CuSO4化学发光体系 ,测定了 2种不同厂家生产的维生素C的抗自由基活性 ,比较了 2种维生素C针剂的自由基清除率 .结果表明 ,该体系可以用于抗自由基活性检测 ,方法简单快速     

用光度法研究在3种溶剂中的硫氰酸钼(V)配合物

报道在3种溶剂中硫氨酸钠（V）配合物的生成情况，并以石油亚砜为萃取剂对其进行萃取研究，讨论了萃取剂的影响和有关萃取机理．     

非线性动力系统理论在机械故障诊断中的应用

从非线性动力系统理论的角度出发，对非线性动力系统进行了分析，据此建立了数学模型，并应用于实际的物理系统中．根据对Ｌｉａｐｕｎｏｖ指数的计算，分析了在非线性问题处理中各方法的优劣及其可靠性．作为尝试，文中试图利用非线性方法对故障进行分类，并对系统进行定性预测分析．实际结果表明在一定程度上是较为成功的     

一种改进的程序分频器

对铷频标中的频率合成器内的程序分频器进行了设计，并介绍了改进后的程序分频器。实验结果表明，该程序分频器用于铷频标的频综器中性能指标满足要求。     

The strong cooperativity of dioxygen binding by dicobalt (II) diporphyrin compounds in nonaqueous solution at room temperature

Thermodynamic data were determined for the reversible binding of O₂ to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge (abbreviated to Co₂PP₈ and Co₂PP₄) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P _1/2) and hill coefficient (n) at 298 K were determined as follows:P _1/2=54.2 kPa,n=2.0 for Co₂PP₈ andP _1/2=6.8 kPa,n=1.8 for Co₂PP₄, respectively. The rate equations of reversible oxygen binding by Co₂PP₈ were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes formed in the solutions are of superoxo (Co-O ₂ ⁻ ) type. Supported by the Research Foundation of the State Education Commission of China Zhou Xiaohai: born in 1962, Ph.D. Associate professor     

Studies on the reaction between Laccase ando-methoxyphenol by microcalorimetry

The reaction between Laccase ando-methoxyphenol have been studied by LKB-2107 batch microcalorimetry system. Thermodynamic parameters Δ _r H _m , ΔG _o , ΔG _T ^≠ and kinetic parameters (K _m ,k ₂) have been determined. The process of the reaction has been analyzed from changes in energy by using the transition state theory. Two methods for enhancing catalytic power of Laccase are proposed. The results shown that formation of an enzyme-substrate complex is “anticatalytic”. The enter and sole source of catalytic power is the stabilization of transition state; reactant-state interactions are by nature inhibitory and only waste catalytic power. Supported by the National Natural Science Foundation of China Wang Tianzhi: born in 1968. Ph D     

全层片组织 TiAl 基合金室温断裂机理的研究

在ＳＥＭ和ＴＥＭ下对Ｔｉ３３Ａｌ３Ｃｒ０．５Ｍｏ合金全层片组织薄板状和薄膜状试样分别进行了动态拉伸，并原位观察了试样中裂纹的形核及扩展过程．发现裂纹遇到内相界面时会发生偏转或裂尖发生钝化；主裂纹主要以使剪切带断裂而与微裂纹相连接的方式扩展并沿曲折路径进行．     

一种ARROW型弯曲波导研究

分别用射线分析法和电磁场分析法，通过保角变换在直角坐标系下研究ＡＲＲＯＷ型弯曲波导特性，导出了其模色散方程（本征模方程）。经优化设计的ＡＲＲＯＷ型弯曲波导结构，使ＴＥ０模的损耗降至为０．０３２９ｃｍ＾－１。